Calculation of the Boundary Dimensions of Functionally Active Nanoparticles

Calculation of the Boundary Dimensions of Functionally Active Nanoparticles

Zulayho A. Smanova, Tokhir Kh. Rakhimov, Muxtarjan Mukhamediev, Dilfuza Gafurova, Dilbar Shaxidova
Copyright: © 2020 |Pages: 9
DOI: 10.4018/IJANR.20200101.oa1
Article PDF Download
Open access articles are freely available for download

Abstract

Size is a key characteristic of nanoparticles that determines whether the objects belong to this category. Currently, there are not enough experiments on materials of the same chemical composition but of different dispersion in particle size, with equal size of the particles or grains of each sample of material investigated. In the present article, the authors show that the effect of the dispersion of the particle size determines whether the size dependence of a specific property can be calculated alternatively to the direct measurements. By finding the correlations between nano-properties and content of nanoparticles' fractions of different sizes, the boundary conditions can be calculated.
Article Preview
Top

Objects Of Experiment

As the quantitative statistical characteristics reflecting the average relative values of the active surface of nanomaterials are prompted to introduce the rms diameter and polydispersity index of nanoparticles (Rakhimov 2014). The question is: from which size dimension of particles some special properties getting acquired, namely are there nano-structure properties appearing, and at what size dimensions are they appearing? What can be considered as a nanoparticle with all their acquired features?

Special drawing catalysts comprising platinum metals, palladium and platinum, as active ingredients, were investigated, Table 1. Fiber polymers - polypropylene fiber, polyacrylonitrile, carbon fibers, low modulus carbon, fibrous materials obtained by carbonization and subsequent activation of mats from “Mtilon-M”, copolymers of polyacrylonitrile and hydrocellulose, were used as bearers.

The possibility of exhaustive removal of toxic components, mainly CO, from air by passive systems has been achieved with advent of nanocatalysts (Rakhimov et al., 2014). A decisive influence of substrates nature on the activity and stability and the process character was determined (Rakhimov et al., 2014; Nurmukhammadov et al., 2014; Smanova et al., 2011; Madusmanova et al., 2020). At the same time, it is obvious that the state and also physical and chemical characteristics of active component will exert not smaller influence on properties of the catalytic system in whole.

Activity of catalysts was determined by decreasing the CO content in gas-air mixture at room temeprature. The rms diameter and coefficient of polydispersity of nanoparticles (Rakhimov 2014) were measured by transmission electron microscopy, Table 1.

Complete Article List

Search this Journal:
Reset
Volume 8: 1 Issue (2025): Forthcoming, Available for Pre-Order
Volume 7: 1 Issue (2024): Forthcoming, Available for Pre-Order
Volume 6: 1 Issue (2021)
Volume 5: 1 Issue (2020)
Volume 4: 2 Issues (2019)
View Complete Journal Contents Listing